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All About Nickel Alloys

Nickel alloys, also known as high-performance alloys, are metals that contain some nickel in their elemental makeup to improve some of their properties and make them better suited for applications outside their typical wheelhouse. Let’s look at everything to do with nickel alloy including where they’re used, the different types, and their characteristics and physical properties.

What is Nickel Alloy?

If a metal contains nickel as one of its primary elements, it’s classified as a nickel alloy. Some types of nickel alloys are even classed as “superalloys” because, if you compare them to other metals, their oxidation and creep resistance is off the charts and allows them to be used at temperatures of over half their melting points. Although not all superalloys are nickel alloys, the vast majority of them are nickel-based.

Not all metals can be mixed with nickel, but some of the most common elements are iron, chromium, aluminum, molybdenum, copper, cobalt, and titanium. To make nickel alloys, you’d have to follow the same process used for pretty much every other metal alloy. The alloying elements need to be decided on, and their ratios need to be carefully chosen. Once that’s done, the elements are all melted together in something like an arc furnace, which also purifies them, and then the alloy is cast into ingots, and off to be formed using either cold or hot processing.

A Brief History

It’s believed that the first nickel alloy was used in 200 BCE in China. That’s the earliest record available, and the material was referred to as “white copper,” which experts believe was an alloy of nickel and silver. Fast forward to 1751, A. F. Cronstedt, a German scientist, managed to isolate nickel from the niccolite mineral. Copper and zinc were often found in these first nickel alloys, which came to be known as “German silver” and weren’t really used for anything other than ornaments.

After James Riley made an iron-chromium alloy in 1913, W. H. Hatfield figured out that adding nickel to these alloys would make them incredibly corrosion-resistant. This led to the creation of what we now know as austenitic stainless steel .

Nickel Alloy Characteristics

Here are the main characteristics of nickel alloys:

  • Corrosion/oxidation resistant
  • High strength
  • Heat resistance up to 980°C
  • Highly ductile, won’t break easily if bent
  • Magnetic, can easily be magnetized and demagnetized
  • Weldability with various welding methods (although could develop hot or warm cracking and porosity)
  • Low thermal conductivity, higher with nickel-copper alloys
  • Low electrical conductivity, less than pure copper or silver
  • Low thermal expansion coefficient, great for precision
  • Varying colors depending on alloying element

It’s generally quite hard to differentiate nickel alloys from other types of metals. Nickel alloys can seem slightly dull when their surface is rough, but when it’s smooth, they can be shiny and reflective.

Types of Nickel Alloys

There are several types of nickel alloys available today. Here’s a list of some of the most common:

Nickel alloy type Composition Characteristics Common subtypes
Nickel-Chromium
Chromium, molybdenum, iron
Oxidation resistance, high mechanical strength, excellent in high-temperature environments, can be hard to cold form due to its quick work-hardening
Inconel, 625, 718, and 600
Nickel-Copper
Copper (55–91.5%), iron, tin, manganese
Saltwater corrosion and fouling resistance, high strength, performs well in low-temperature environments (its ductility won’t reduce and its strength and hardness can increase), can work harden during cold forming
Monel 400, R-405, and K-500
Nickel-Molybdenum
Either chromium or molybdenum
Great thermal stability, corrosion- and oxidation-resistance at high temperatures
Hastelloy, C-22, and C-276
Nickel-Iron
Iron, nickel (up to 50%), cobalt, small amounts of silicon
High ductility, low thermal expansion, corrosion resistance, soft magnetic properties
Invar
Nickel-Chromium
High nickel content of around 70%
Maintain strength in high temperatures, very good corrosion and oxidation resistance, as well as high electrical resistivity, high melting point of over 1300°C
Nichrome
Nickel-Titanium
Nickel, titanium
Great corrosion resistance and mechanical strength. This is a shape memory alloy (SMA) that can be formed into a shape above a certain high temperature (the transition temperature). When it cools, the part can be deformed to a certain extent, but when heated back up to the transition temperature, it will resume its original shape. The transition temperature can be adjusted by changing the alloy’s composition
Nitinol

Types of Nickel Alloys

Properties

In the table below, we list some of the key properties of nickel alloys:

Property Type Benefits Applications
Ultimate Tensile Strength [MPa]
Inconel 625
Excellent corrosion and oxidation resistance, high creep strength
Turbine blades and other aerospace components
Curie Temperature [°C]
Invar 36
Low thermal conductivity
Tooling, dies, cryogenic components
Coefficient of Linear Thermal Expansion @ @ 93 °C (Annealed) (µm/µm·°C)
Invar 36
High melting temperature
Tooling, dies, cryogenic components
Thermal Conductivity @ 93 °C (Annealed) (W/m·K)
Monel 400
Excellent saltwater resistance and low-temperature strength
Process vessels, process piping, pumps

Nickel Alloy Properties

Chemical Properties

Now that we’ve gone through some of the physical properties of nickel alloys, let’s take a closer look at their chemical properties:

Type Corrosion Resistance Oxidation Resistance Main Alloying Elements Magnetic Heat Resistance [Solidus] °C
Inconel 625
Very resistant to pitting, chloride ion stress corrosion cracking, and crevice corrosion
Highly resistant to oxidation at elevated temperatures
Ni – 58% / Cr – 20 to 23% / Fe – 5% / Nb,Ta – 3.15 to 4.15%
No
1290
Hastelloy 276
Very resistant to pitting, chloride ion stress corrosion cracking, and crevice corrosion
Highly resistant to oxidation at elevated temperatures
Ni – 57% / Mo – 15 to 17% / Cr – 14.5 to 16.5% / Fe – 4 to 7% / Co – 2.5% / Mn – 1%
No
1323
Invar 36
Not resistant to corrosion due to high iron content, must be nickel-plated to improve corrosion resistance
Not really resistant to oxidation due to its iron content when compared to other nickel alloys
Fe – 63% / Ni – 36%
Yes
1427
Monel 400
Highly resistant to saltwater environments
Some Monel grades can have good high-temperature oxidation resistance
Ni – 63% / Cu – 28 to 34% / Fe – 2.5% / Mn – 2%
No
1300
Nichrome 35-20
Not very corrosion-resistant
Not very resistant to oxidation
Fe – 42% / Ni – 35% / Cr – 20% / Si – 2% / Mn – 1%
No
1390

Nickel Alloy Chemical Properties Table Credit: https://matweb.com/

Physical Property Comparison

In this table, we break down and compare the physical properties associated with some of the most common types of nickel alloys:

Property Inconel 625 Hastelloy 276 Invar 36 Monel 400 Nichrome 35-20
Density [g/cm3]
8.44
8.89
8.05
8.8
7.9
Ultimate Tensile Strength [MPa]
689–1103
601.2–826.7
621
450–550
750
Curie Temperature [°C]
-196
-269>26.85
279
20–50
N/A
Melting Temperature [°C]
1290–1350
1323–1271
1427
1300–1350
1390
Electrical Resistivity @ 93 °C (Annealed) [µΩ·cm]
132
130
82
54.7
104
Coefficient of Linear Thermal Expansion @ 93 °C (Annealed) (µm/µm·°C)
13
11.2
1.3
13.9
19
Thermal Conductivity @ 93 °C (Annealed) (W/m·K)
10.8
11.1
10.15
21.8
13
Specific Heat @ 93°C (Annealed) (J/kg·°C)
427
427
515
427
500

Nickel Alloys Physical Property Comparison Table Credit: https://matweb.com/

Nickel Alloys: Applications

Nickel alloys are used in so many sectors. Here are some of their most common applications:

Application Description
Aerospace
This is one of the most common applications for nickel alloys because of the high operating temperatures that are so common on aerospace equipment. Rocket engine parts and turbine blades are often made from Inconel.
Chemical processing
It’s very common for this sector to require materials that are highly resistant to corrosion environments and substances. Nickel alloys are often used here for things like tanks, piping, and mixing devices.
Oil & gas
Understandably, any materials exposed to oil and gas will need the ability to withstand high temperatures, high pressures, and corrosive environments. That’s why nickel alloys fit the bill. They’re often used to make pumps, pipes, pressure vessels, and heat exchangers.
Medical
Alloys are suitable for medical equipment that goes through regular sterilization at high temperatures or some sort of solvent. They’re also used for orthopedic implants and stents, thanks to the SMA properties
Electrical/ electronics
Some nickel alloys are electrically conductive and resistant to corrosion, making them great for electrical contacts in corrosive environments. Others feature low coercivity, making them perfect for soft magnetic applications like memory storage units or transformers.
Marine
Marine environments can be extremely corrosive and not many alloys can withstand that, especially with prolonged exposure to saltwater and salt spray. Nickel alloys, especially if they’ve got lots of copper in them, are made for the job. They’re often used to make propellers, bilge pumps, and valves.
Precision Instruments
These often need a low coefficient of thermal expansion to reduce temperature effects. An alloy with a low thermal expansion can be used alongside a metal with high thermal expansion, then joined into a bimetal strip that can be used as a temperature switch. Examples include hermetic seals found in X-ray tubes.

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Post time: Jan-16-2026