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Overall corrosion of nickel and its corrosion resistant alloys in high temperature hydrogen fluoride—full corrosion (6)

HF gas is a common medium for certain chemical processing. In high temperature hydrogen fluoride, Ni201, monel400, inconel 600, C-276 and 00Cr16Ni65Mo2Ti alloys all have suitable corrosion resistance, and have been successfully applied to practical engineering. Some corrosion test data are shown in Table 2-24 and Table 2-25.

Fig. 2-23 and Fig. 2-27 are corrosion test results of some corrosion-resistant alloys in high-temperature HF gas. Obviously, in various HF gases, Monel 400, NS 3301 (00Cr16Ni75Mo2Ti), and NS 3304 (C-276) three The best corrosion resistance of the alloy. However, in the HF above 600 oC, intergranular corrosion occurs in the Monel 400 alloy. In contrast, NS3301 and NS 3304 do not suffer from intergranular corrosion.

Note: In Figure 2-24, Figure 2-25, Figure 2-26, and Figure 2-27, the ratio of HF to H 2 O is the mass ratio, and the ratio of aqueous HF to air is the volume ratio.

2-24 Corrosion of Ni200 and Monel 400 in Mixture of Hydrogen Fluoride and Water Vapor

Grade

corrosion average rate/ mm﹒a⁻¹

550ºC

600ºC

650ºC

700ºC

750ºC

Nickel 201

0.79

1.83

2.74

3.66

3.05

monel 400

/

0.61

1.52

3.96

5.18

2-25 Corrosion of Ni200 and Some Corrosion Resistant Alloys in Hydrogen Peroxide at 500~600 degrees celsius.

Grade

time/h

corrosion average rate/ mm﹒a⁻¹

C-276

36

0.0075

600

36

0.0175

200

36

0.225

201

36

0.35

400

36

0.325

K-500

36

0.4

70/30 Cu-Ni

36

0.4

2-26 Corrosion resistance of some metallic materials in dry chlorine

Grade

temperature ºC

Max temperature ºC

0.76mm/a

1.52mm/a

3.05mm/a

Ni201

510

538

593

538

600

510

538

565

538

C-276

482

538

565

510

400

399

454

482

426

316 stainless steel

315

343

399

343

304 stainless steel

288

315

343

315

CuO₂

177

232

/

204

Carbon

121

177

204

204

Al

121

149

149

121

2-27 Corrosion of Some Metallic Materials in Dry HCI

Grade

Short-term experiments in dry HCI with corrosion rates exceeding the approximate temperatures for a given corrosion rate

Temperatue /ºC

0.76mm/a

1.52mm/a

3.05mm/a

Ni201

454

510

565

510

600

426

482

538

482

C-276

371

426

482

452

316 stainless steel

371

371

482

426

304 stainless steel

343

399

454

399

Carbon

260

315

399

260

Monel 400

232

260

343

232

Cu

93

149

204

93

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Post time: May-11-2018